Product ID:SUN LARGE TABLETS, CPE710126
MSDS Date:08/25/1992
FSC:6850
NIIN:00N050735
MSDS Number: BVNXN

OLIN CORPORATION

120 LONG RIDGE ROAD
STAMFORD, CT 06904
US

Emergency Phone: 800-654-6911

Info Phone: 203-356-3449

Cage: 0G578

OLIN CORPORATION

STAMFORD, CT 06904-1355 US

Telephone: 203-356-3449

Cage: 0G578

SOURCE AS SOON AS POSS. BEGIN MONITORING FOR AVAIL

RTECS: 9999999ZZ

ANY ORG MATLS, AMMONIA, SALTS/UREA. CLEAN UP ALL

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DRY CNTNR. DISP OF PER GUIDELINES. MATL MAY BE NEUT

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BEGINNING ANY SUCH OPERATION.

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STATE & FED REGS IN PERMITTED HAZ WASTE

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BE TAKEN TO PVNT ENVIRON CONTAM FROM USE OF THIS

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UNUSED MATL, RESIDUES & CNTNRS IN COMPLIANCE W/ALL

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TREATMENT, STOR & DISP FOR HAZ & NONHAZ WASTES.

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CARTRIDGES FOR PROT AGAINST CHLORINE GAS &

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AVOID EYE & SKIN CONT. EYE WASH STATION &

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SHOULD BE PROVIDED IN IMMEDIATE WORK AREA.

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MATL IS

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2-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE, 1,3,5-TRICHLORO-;

CAS: 87-90-1

RTECS: XZ1925000

Fraction By Weight: 96-100%

OSHA PEL N/K

ACGIH TLV: N/K

S-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE, 1,3-DICHLORO-;

CAS: 2782-57-2

RTECS: XZ1845000

Fraction By Weight: 0-4%

OSHA PEL N/K

ACGIH TLV: N/K

CHARACT BY NAUS, VOMIT, DIARR, ABDOM PAIN, BLEEDING

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CAUSE IMPAIRMENT OF LUNG FUNC & PERM LUNG DMG.

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EXPOS EXCEPT FOR EFTS SECONDARY TO TISS DESTRUCT.

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MOVE TO FRESH AIR UNTIL SYMPS

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AT REST. CALL MD. IN EVENT THAT INDIVIDUAL INHALES

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TO FRESH AIR AT ONCE & MD SHOULD BE CALLED IMMED. IF

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ALL CASES, ENSURE ADEQ VENT & PROVIDE NIOSH/MSHA

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LD50 LC50 Mixture:LD50:(ORAL,RAT) 490 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED/INGESTED/EXPOSED TO
SKIN/EYES. TCCA HAS POTNTL TO BE IMMED DANGEROUS TO LIFE & HLTH.
ACUTE:INHAL:IRRIT TO NOSE, MOUTH, THROAT & LUNGS. MAY ALSO CAUSE
BURNS TO RESP TRACT W/PROD OF L UNG EDEMA WHICH CAN RSLT IN
SHORTNESS OF BREATH, WHEEZING, CHOKING, CHEST PAIN & IMPAIRMENT OF
LUNG (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:FUNC. INHAL OF HIGH CONCS CAN RSLT IN
PERM DMG. EYE:SEV IRRIT &/OR BURNS CAN OCCUR FOLLOWING EXPOS. CONT
MAY CAUSE IMPAIRMENT OF VISION & CORNEAL DMG. SKIN:CAN CAUSE SEV
IRRIT &/OR BURNS CHAR ACT BY REDNESS, SWELL & SCAB FORM. PRLNG
EXPOS MAY CAUSE DESTRUCT OF DERMIS W/IMPAIRMENT OF SKIN AT SITE OF
CONT(SUPDAT)
Medical Cond Aggravated by Exposure:ASTHMA, RESPIRATORY & CVS DISEASE.

First Aid:EYES:IMMED FLUSH W/LG AMTS OF WATER FOR AT LST 15 MINS, OCCAS
LIFTING UPPER & LOWER EYELIDS. CALL MD AT ONCE. SKIN:IMMED FLUSH
W/WATER FOR AT LST 15 MINS. CALL MD. IF CLTHG COMES IN CONT W/PROD,
CLTHG SHOULD BE REMOVED IMMED & LAUNDERED BEFORE RE-USE.
INGEST:IMMED DRINK LG QTYS OF WATER. DO NOT INDUCE VOMIT. CALL MD
AT ONCE. DO NOT GIVE ANYTHING BY MOUTH IF PERS IS UNCON/IF HAVING
CONVLS. (ING 6)

Extinguishing Media:ON SMALL FIRES, USE WATER SPRAY OR FOG. ON LARGE
FIRES, USE HEAVY DELUGE OR FOG STREAMS.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
USE WATER TO COOL CNTNRS EXPOS TO FIRE. FLOODING AMTS OF WATER MAY
BE REQD BEFORE EXTINGUISHMENT (SUPDAT)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:HAZ CONCS IN AIR MAY BE FOUND IN LOC SPILL
AREA & IMMED DOWNWIND. IF SPILL MATL IS STILL DRY, DO NOT PUT WATER
DIRECTLY ON THIS PROD AS GAS EVOLUTION MAY OCCUR. IF MATL IS WET,
CONT MFR FOR PROPER STA BILIZATION PROCS. AIR:VAPS MAY BE (ING 10)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT TAKE INTERNALLY. AVOID CONT
W/SKIN, EYES & CLTHG. STORE IN CLEAN, DRY, WELL VENTILATED AREA.
KEEP AWAY FROM INCOMPAT CHEMS.
Other Precautions:DO NOT STORE AT TEMPS >60C (140F). INDEFINITE SHELF
LIFE LIMITATIONS. AVAIL CHLORINE LOSS CAN BE AS LITTLE AS 0.1% PER
YR AT AMBIENT TEMPS. PAPER & CARDBOARD ARE INCOMPAT MATLS FOR
PACKAGING.

Respiratory Protection:WEAR NIOSH/MSHA APPRVD RESP EQUIPPED W/CHEM
CARTRIDGE FOR PROT AGAINST CHLORINE GAS & DUST/MIST TYPE PREFILTER.
RESP TYPE:HALF-FACE MASK WORN W/CHEM SFTY GOGGS/FULL FACE RESP WORN
W/OUT. EITHER RESP M UST BE EQUIPPED W/CHEM (ING 19)
Ventilation:USE LOCAL EXHAUST VENTILATION TO MINIMIZE DUST LEVELS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM (WORK HYGENIC PRAC)
Other Protective Equipment:WEAR BOOTS, APRONS/IMPERMEABLE SUIT
(NEOPRENE, CHLORINATED POLYETHYLENE, BUTLY RUBBER, SARANEX) & HARD
HAT TO (ING 20)
Work Hygienic Practices:UPON CONTACT W/SKIN OR EYES, WASH OFF W/WATER.
EYE PROTECTION: WORKER GOGGLES WITH FULL LENGTH FACESHIELD .
Supplemental Safety and Health
PH:2.7-2.9(OF 1% SOLN). FIRE FIGHT PROC:CAN BE ACCOMPLISHED. DO NOT USE
DRY CHEM EXTINGS CNTNG AMMONIA CMPDS. CNDTNS(STAB):WET PROD(WILL
EVOLVE NITROGEN TRICHLORIDE). MATLS TO AVOID:EXTINGS CNTNG AMMO
NIUM CMPDS. EFTS OF OVEREXP:TO REGENERATE. INGEST:IRRIT &/OR BURNS
CAN OCCUR TO GI TRACT, INCL STOM & INTESTINES,(ING 3)

Spec Gravity:>1
pH:SUPDAT
Solubility in Water:1.2% @ 25C
Appearance and Odor:WHITE, GRANULAR SOLID OR TABLET-FORM PRODUCT;
SHARP, CHLORINE-LIKE BLEACH ODOR.

Stability Indicator/Materials to Avoid:NO
ORG MATLS, OILS, GREASE, SAWDUST, REDUCING AGENTS, NITROGEN CNTNG
CMPDS, OTHER OXIDIZERS, ACIDS, BASES, DRY FIRE(SUPDAT)
Stability Condition to Avoid:TEMPS >225C(437F). CONT W/SM AMTS OF WATER
MAY RSLT IN EXOTHERMIC RXN W/LIBERATION OF TOX FUMES. DAMP/SLIGHTLY
(SUPDAT)
Hazardous Decomposition Products:NITROGEN TRICHLORIDE, CHLORINE,
NITROUS OXIDES, CYANATES, CARBON MONOXIDE, CARBON DIOXIDE.

Waste Disposal Methods:IF PROD BECOMES WASTE, IT MEETS CRITERIA OF HAZ
WASTE AS DEFINED UNDER 40CFR261 & WOULD HAVE EPA HAZ #D001 & IS
SUBJECT TO LAND DISP RESTRICTIONS UNDER 40CFR268 & MUST BE MANAGED
ACCORDINGLY. AS HAZ S OLID WASTE, IT MUST BE DISP OF I/A/W LOC,
(ING 15)

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of Defense. The United States of America in no manner whatsoever,
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particular situation.